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Season 1 Sep. 30, 2001
- Episode 1: Truth Be Told
- Episode 2: So It Begins
- Episode 3: Parity
- Episode 4: A Broken Heart
- Episode 5: Doppelgänger
- Episode 6: Reckoning
- Episode 7: Color-Blind
- Episode 8: Time Will Tell
- Episode 9: Mea Culpa
- Episode 10: Spirit
- Episode 11: The Confession
- Episode 12: The Box (1)
- Episode 13: The Box (2)
- Episode 14: The Coup
- Episode 15: Page 47
- Episode 16: The Prophecy
- Episode 17: Q & A
- Episode 18: Masquerade
- Episode 19: Snowman
- Episode 20: The Solution
- Episode 21: Rendezvous
- Episode 22: Almost Thirty Years
Season 2 Sep. 29, 2002
- Episode 1: The Enemy Walks In
- Episode 2: Trust Me
- Episode 3: Cipher
- Episode 4: Dead Drop
- Episode 5: The Indicator
- Episode 6: Salvation
- Episode 7: The Counteragent
- Episode 8: Passage (1)
- Episode 9: Passage (2)
- Episode 10: The Abduction
- Episode 11: A Higher Echelon
- Episode 12: The Getaway
- Episode 13: Phase One
- Episode 14: Double Agent
- Episode 15: A Free Agent
- Episode 16: Firebomb
- Episode 17: A Dark Turn
- Episode 18: Truth Takes Time
- Episode 19: Endgame
- Episode 20: Countdown
- Episode 21: Second Double
- Episode 22: The Telling
Season 3 Sep. 28, 2003
- Episode 1: The Two
- Episode 2: Succession
- Episode 3: Reunion
- Episode 4: A Missing Link
- Episode 5: Repercussions
- Episode 6: The Nemesis
- Episode 7: Prelude
- Episode 8: Breaking Point
- Episode 9: Conscious
- Episode 10: Remnants
- Episode 11: Full Disclosure
- Episode 12: Crossings
- Episode 13: After Six
- Episode 14: Blowback
- Episode 15: Façade
- Episode 16: Taken
- Episode 17: The Frame
- Episode 18: Unveiled
- Episode 19: Hourglass
- Episode 20: Blood Ties
- Episode 21: Legacy
- Episode 22: Resurrection
Season 4 Jan. 05, 2005
- Episode 1: Authorized Personnel Only (1)
- Episode 2: Authorized Personnel Only (2)
- Episode 3: The Awful Truth
- Episode 4: Ice
- Episode 5: Welcome To Liberty Village
- Episode 6: Nocturne
- Episode 7: Détente
- Episode 8: Echoes
- Episode 9: A Man of His Word
- Episode 10: The Index
- Episode 11: The Road Home
- Episode 12: The Orphan
- Episode 13: Tuesday
- Episode 14: Nightingale
- Episode 15: Pandora
- Episode 16: Another Mister Sloane
- Episode 17: A Clean Conscience
- Episode 18: Mirage
- Episode 19: In Dreams...
- Episode 20: The Descent
- Episode 21: Search and Rescue
- Episode 22: Before the Flood
Season 5 Sep. 29, 2005
- Episode 1: Prophet Five
- Episode 2: ...1...
- Episode 3: The Shed
- Episode 4: Mockingbird
- Episode 5: Out of the Box
- Episode 6: Solo
- Episode 7: Fait Accompli
- Episode 8: Bob
- Episode 9: The Horizon
- Episode 10: S.O.S.
- Episode 11: Maternal Instinct
- Episode 12: There's Only One Sydney Bristow
- Episode 13: 30 Seconds
- Episode 14: I See Dead People
- Episode 15: No Hard Feelings
- Episode 16: Reprisal
- Episode 17: All The Time In The World
Alias Season 4 Episode 19
The team captures the Sloane Imposter and questions him to find a rare Rambaldi orchid. The real Sloane must relive a painful memory in order to get the Imposter to reveal the orchid location.