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Season 1 Sep. 20, 2010
- Episode 1: Pilot
- Episode 2: First Date
- Episode 3: First Kiss
- Episode 4: Mike's Not Ready
- Episode 5: Carl Is Jealous
- Episode 6: Mike's Apartment
- Episode 7: After the Lovin'
- Episode 8: Mike Snores
- Episode 9: Mike's New Boots
- Episode 10: Molly Gets A Hat
- Episode 11: Carl Gets A Girl
- Episode 12: First Christmas
- Episode 13: Mike Goes to the Opera
- Episode 14: Molly Makes Soup
- Episode 15: Jim Won't Eat
- Episode 16: First Valentine's Day
- Episode 17: Joyce & Vince and Peaches & Herb
- Episode 18: Mike's Feet
- Episode 19: Peggy Shaves Her Legs
- Episode 20: Opening Day
- Episode 21: Samuel Gets Fired
- Episode 22: Cigar Talk
- Episode 23: Victoria's Birthday
- Episode 24: Peggy's New Beau
Season 2 Sep. 26, 2011
- Episode 1: Goin' Fishin'
- Episode 2: Dennis's Birthday
- Episode 3: Mike in the House
- Episode 4: '57 Chevy Bel Air
- Episode 5: Victoria Runs Away
- Episode 6: Happy Halloween
- Episode 7: Carl Meets a Lady
- Episode 8: Peggy Gets A Job
- Episode 9: Mike Cheats
- Episode 10: Molly Needs a Number
- Episode 11: Christmas Break
- Episode 12: Carl Has Issues
- Episode 13: Victoria Can't Drive
- Episode 14: Joyce's Choices
- Episode 15: Valentine's Piggyback
- Episode 16: Surprise
- Episode 17: Mike Likes Lasagna
- Episode 18: Peggy Goes to Branson
- Episode 19: Molly Can't Lie
- Episode 20: The Dress
- Episode 21: Bachelor/Bachelorette
- Episode 22: The Rehearsal
- Episode 23: The Wedding
Season 3 Sep. 23, 2012
- Episode 1: The Honeymoon is Over
- Episode 2: Vince Takes A Bath
- Episode 3: Mike Likes Cake
- Episode 4: Molly in the Middle
- Episode 5: Mike's Boss
- Episode 6: Yard Sale
- Episode 7: Thanksgiving Is Cancelled
- Episode 8: Mike Likes Briefs
- Episode 9: Mike Takes a Test
- Episode 10: Karaoke Christmas
- Episode 11: Fish for Breakfast
- Episode 12: Molly’s Birthday
- Episode 13: Carl Gets a Roommate
- Episode 14: The Princess and the Troll
- Episode 15: Mike the Tease
- Episode 16: Molly's New Shoes
- Episode 17: St. Patrick's Day
- Episode 18: Spring Break
- Episode 19: Party Planners
- Episode 20: Mike Can't Read
- Episode 21: Molly’s Out of Town
- Episode 22: School Recital
- Episode 23: Windy City
Season 4 Nov. 03, 2013
- Episode 1: Molly Unleashed
- Episode 2: The First and Last Ride-Along
- Episode 3: Sex and Death
- Episode 4: Careful What You Dig For
- Episode 5: Poker in the Front, Looker in the Back
- Episode 6: Shoeless Molly Flynn
- Episode 7: They Shoot Asses, Don't They?
- Episode 8: What Molly Hath Wrought
- Episode 9: Mike & Molly's Excellent Adventure
- Episode 10: Weekend at Peggy's
- Episode 11: Dips & Salsa
- Episode 12: Mind Over Molly
- Episode 13: Open Mike Night
- Episode 14: Rich Man, Poor Girl
- Episode 15: Three Girls and an Urn
- Episode 16: The Dice Lady Cometh
- Episode 17: McMillan and Mom
- Episode 18: Mike's Manifold Destiny
- Episode 19: Who's Afraid of J.C. Small?
- Episode 20: Sex, Lies and Helicopters
- Episode 21: This Old Peggy
- Episode 22: Eight Is Enough
Season 5 Dec. 07, 2014
- Episode 1: The Book of Molly
- Episode 2: To Have and Withhold
- Episode 3: 'Tis the Season to Be Molly
- Episode 4: Gone Cheatin'
- Episode 5: Molly's Neverending Story
- Episode 6: The Last Temptation of Mike
- Episode 7: Support Your Local Samuel
- Episode 8: Mike Check
- Episode 9: Hack to the Future
- Episode 10: Checkpoint Joyce
- Episode 11: Immaculate Deception
- Episode 12: The World According to Peggy
- Episode 13: Buy The Book
- Episode 14: Whatever Happened to Baby Peggy
- Episode 15: Pie Fight
- Episode 16: Cocktails and Calamine
- Episode 17: Mudlick or Bust
- Episode 18: No Kay Morale
- Episode 19: Mother From Another Mudlick
- Episode 20: Fight To The Finish
- Episode 21: Near Death Do Us Part
- Episode 22: The Bitter Man and the Sea
Season 6 Jan. 05, 2016
- Episode 1: Cops on the Rocks
- Episode 2: One Small Step for Mike
- Episode 3: Peg O' My Heart Attack
- Episode 4: Super Cop
- Episode 5: Joyce's Will Be Done
- Episode 6: The Good Wife
- Episode 7: Weekend With Birdie
- Episode 8: The Wreck of the Vincent Moranto
- Episode 9: Baby, Please Don't Go
- Episode 10: Baby Bump
- Episode 11: The Adoption Option
- Episode 12: Curse of the Bambino
- Episode 13: I See Love
Mike & Molly Season 1 Episode 20
Mike breaks tradition and invites Molly to join him and Carl at opening day for the Chicago Cubs.