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Season 1 Sep. 20, 2010
- Episode 1: Pilot
- Episode 2: First Date
- Episode 3: First Kiss
- Episode 4: Mike's Not Ready
- Episode 5: Carl Is Jealous
- Episode 6: Mike's Apartment
- Episode 7: After the Lovin'
- Episode 8: Mike Snores
- Episode 9: Mike's New Boots
- Episode 10: Molly Gets A Hat
- Episode 11: Carl Gets A Girl
- Episode 12: First Christmas
- Episode 13: Mike Goes to the Opera
- Episode 14: Molly Makes Soup
- Episode 15: Jim Won't Eat
- Episode 16: First Valentine's Day
- Episode 17: Joyce & Vince and Peaches & Herb
- Episode 18: Mike's Feet
- Episode 19: Peggy Shaves Her Legs
- Episode 20: Opening Day
- Episode 21: Samuel Gets Fired
- Episode 22: Cigar Talk
- Episode 23: Victoria's Birthday
- Episode 24: Peggy's New Beau
Season 2 Sep. 26, 2011
- Episode 1: Goin' Fishin'
- Episode 2: Dennis's Birthday
- Episode 3: Mike in the House
- Episode 4: '57 Chevy Bel Air
- Episode 5: Victoria Runs Away
- Episode 6: Happy Halloween
- Episode 7: Carl Meets a Lady
- Episode 8: Peggy Gets A Job
- Episode 9: Mike Cheats
- Episode 10: Molly Needs a Number
- Episode 11: Christmas Break
- Episode 12: Carl Has Issues
- Episode 13: Victoria Can't Drive
- Episode 14: Joyce's Choices
- Episode 15: Valentine's Piggyback
- Episode 16: Surprise
- Episode 17: Mike Likes Lasagna
- Episode 18: Peggy Goes to Branson
- Episode 19: Molly Can't Lie
- Episode 20: The Dress
- Episode 21: Bachelor/Bachelorette
- Episode 22: The Rehearsal
- Episode 23: The Wedding
Season 3 Sep. 23, 2012
- Episode 1: The Honeymoon is Over
- Episode 2: Vince Takes A Bath
- Episode 3: Mike Likes Cake
- Episode 4: Molly in the Middle
- Episode 5: Mike's Boss
- Episode 6: Yard Sale
- Episode 7: Thanksgiving Is Cancelled
- Episode 8: Mike Likes Briefs
- Episode 9: Mike Takes a Test
- Episode 10: Karaoke Christmas
- Episode 11: Fish for Breakfast
- Episode 12: Molly’s Birthday
- Episode 13: Carl Gets a Roommate
- Episode 14: The Princess and the Troll
- Episode 15: Mike the Tease
- Episode 16: Molly's New Shoes
- Episode 17: St. Patrick's Day
- Episode 18: Spring Break
- Episode 19: Party Planners
- Episode 20: Mike Can't Read
- Episode 21: Molly’s Out of Town
- Episode 22: School Recital
- Episode 23: Windy City
Season 4 Nov. 03, 2013
- Episode 1: Molly Unleashed
- Episode 2: The First and Last Ride-Along
- Episode 3: Sex and Death
- Episode 4: Careful What You Dig For
- Episode 5: Poker in the Front, Looker in the Back
- Episode 6: Shoeless Molly Flynn
- Episode 7: They Shoot Asses, Don't They?
- Episode 8: What Molly Hath Wrought
- Episode 9: Mike & Molly's Excellent Adventure
- Episode 10: Weekend at Peggy's
- Episode 11: Dips & Salsa
- Episode 12: Mind Over Molly
- Episode 13: Open Mike Night
- Episode 14: Rich Man, Poor Girl
- Episode 15: Three Girls and an Urn
- Episode 16: The Dice Lady Cometh
- Episode 17: McMillan and Mom
- Episode 18: Mike's Manifold Destiny
- Episode 19: Who's Afraid of J.C. Small?
- Episode 20: Sex, Lies and Helicopters
- Episode 21: This Old Peggy
- Episode 22: Eight Is Enough
Season 5 Dec. 07, 2014
- Episode 1: The Book of Molly
- Episode 2: To Have and Withhold
- Episode 3: 'Tis the Season to Be Molly
- Episode 4: Gone Cheatin'
- Episode 5: Molly's Neverending Story
- Episode 6: The Last Temptation of Mike
- Episode 7: Support Your Local Samuel
- Episode 8: Mike Check
- Episode 9: Hack to the Future
- Episode 10: Checkpoint Joyce
- Episode 11: Immaculate Deception
- Episode 12: The World According to Peggy
- Episode 13: Buy The Book
- Episode 14: Whatever Happened to Baby Peggy
- Episode 15: Pie Fight
- Episode 16: Cocktails and Calamine
- Episode 17: Mudlick or Bust
- Episode 18: No Kay Morale
- Episode 19: Mother From Another Mudlick
- Episode 20: Fight To The Finish
- Episode 21: Near Death Do Us Part
- Episode 22: The Bitter Man and the Sea
Season 6 Jan. 05, 2016
- Episode 1: Cops on the Rocks
- Episode 2: One Small Step for Mike
- Episode 3: Peg O' My Heart Attack
- Episode 4: Super Cop
- Episode 5: Joyce's Will Be Done
- Episode 6: The Good Wife
- Episode 7: Weekend With Birdie
- Episode 8: The Wreck of the Vincent Moranto
- Episode 9: Baby, Please Don't Go
- Episode 10: Baby Bump
- Episode 11: The Adoption Option
- Episode 12: Curse of the Bambino
- Episode 13: I See Love
Mike & Molly Season 1 Episode 22
When Joyce invites Vince to attend her high school reunion, Vince confesses to Mike that he never graduated high school, and convinces Mike to help him study for his GED.